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• Metal Clusters in Solution
  • 2009

    • Functionalization of Nine-Atom Deltahedral Zintl Ions with Organic Substituents: Detailed Studies of the Reactions Michael W. Hull and Slavi C. Sevov J. Am. Chem. Soc. 2009, 131, 9026-9037 (4.3 MB)

    • Heteroatomic Deltahedral Zintl Ions of Group 14 and their Alkenylation Miriam M. Gillett-Kunnath, Ivaylo Petro and Slavi C. Sevov Inorg. Chem. 2009, asap, Dec 15 (3.6 MB)

  • 2008

    • Tin Zintl Ions: Synthesis, Structure, and Reactivity, Slavi C. Sevov in Tin Chemistry: Fundamentals, Frontiers, and Applications, Eds.: Marcel Gielen, Alwyn Davies, Keith Pannell, Edward Tiekink, Wiley-VCH, 2008, pp. 138-150 (1.1 MB)

    • Tin-Based Organo-Zintl Ions: Alkylation and Alkenylation of Sn94- Donald J. Chapman and Slavi C. Sevov Inorg. Chem. 2008, 47, 6009-6013 (267 KB)

  • 2007

    • Organo-Zintl Clusters Soluble in Conventional Organic Solvents: Setting the Stage for Organo-Zintl Cluster Chemistry Michael W. Hull and Slavi C. Sevov Inorg. Chem. 2007, 46, 10953 (68 KB)

    • Addition of Alkenes to Deltahedral Zintl Clusters by Reaction with Alkynes: Synthesis and Structures of [Fc-CH=CH-Ge9-CH=CH-Fc]2-, an Organo-Zintl-Organometallic Anion Michael W. Hull and Slavi C. Sevov Angew. Chem. Int. Ed. 2007, 46, 6695 (144 KB)

    • Heteroatomic Deltahedral Clusters: Synthesis and Structures of closo-[Bi3Ni4(CO)6]3-, closo-[Bi4Ni4(CO)6]2-, the Open Cluster [Bi3Ni6(CO)9]3-, and the Intermetalloid closo-[Nix@{Bi6Ni6(CO)8}]4- Jose M. Goicoechea, Michael W. Hull, and Slavi C. Sevov J. Am. Chem. Soc 2007, 129, 7885-7893 (324 KB)

    • Alkylation of Deltahedral Zintl Clusters: Synthesis of [R-Ge9-Ge9-R]4- (R = tBu, sBu, nBu, tAm) and Structure of [tBu-Ge9-Ge9-tBu]4- Michael W. Hull, Angel Ugrinov, Ivaylo Petrov, and Slavi C. Sevov Inorg. Chem. 2007, 46, 2704 (112 KB)

  • 2006

    • Chemistry of Deltahedral Zintl Ions Slavi C. Sevov and Jose M. Goicoechea Organometallics 2006, 25, 5678 (6 MB)

    • [Zn9Bi11]5-: A Ligand-Free Intermetalloid Cluster Jose M. Goicoechea and Slavi C. Sevov, Angew. Chem. Int. Ed. 2006, 45, 5147 (236 KB)

    • Organozinc Derivatives of Deltahedral Zintl Ions: Synthesis and Characterization of closo-[E9Zn(C6H5)]3- Jose M. Goicoechea and Slavi C. Sevov, Organometallics 2006, 25, 4530 (244 KB)

    • Deltahedral Germanium Clusters: Insertion of Transition-Metal Atoms and Addition of Organometallic Fragments. Jose M. Goicoechea and Slavi C. Sevov, J. Am. Chem. Soc. 2006, 128, 4155 (193 KB)

  • 2005

    • Synthesis of a chain of nine-atom germanium clusters accompanied with dimerization of the sequestering agent. Angel Ugrinov, Slavi C. Sevov, C. R. Chimie 2005, 8, 1878 (280 KB)

    • [(Ni-Ni-Ni)@(Ge9)2]4-: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters. Jose M. Goicoechea and Slavi C. Sevov, Angew. Chem. Int. Ed. 2005, 127, 4026 (369 KB)

    • [(Pd-Pd)@Ge18]4-: A Palladium Dimer Inside the Largest Single-Cage Deltahedral Cluster. Jose M. Goicoechea and Slavi C. Sevov, J. Am. Chem. Soc. 2005, 127, 7676 (129 KB) Highlighted in: Science 2005, 305, 1088 (Editor's Choice section, May 20).

    • Ligand-Free Deltahedral Clusters of Silicon in Solution: Synthesis, Structure, and Electrochemistry os Si92-. Jose M. Goicoechea and Slavi C. Sevov, Inorg. Chem. 2005, 44, 2654 (108 KB)

    • Analysis of the Effect of Spin-Orbit Coupling on the Electronic Structure and Excitation Spectrum of the Bi22- anion in (K-crypt)2Bi2 on the Basis of Relativistic Electronic Structure Calculations. D. Dai, M.-H. Whangbo, A. Ugrinov, S. C. Sevov, F. Wang, L. Li, A. Villesuzanne, A. B. Alekseyev, H.-P. Liebermann, R. J. Buenker, J. Phys. Chem. A 2005, 109, 1675 (231 KB)

  • 2004

    • Naked Deltahedral Silicon Clusters in Solution: Synthesis and Characterization of Si93- and Si52-. Goicoechea, J. M.; Sevov, S.C. J. Am. Chem. Soc. 2004, 126(22), 6860-6861 (38.8 KB) Highlighted in: Chemistry & Industry 2004, June 21, p. 30

    • Rationally Functionalized Deltahedral Zintl Ions: Synthesis and Characterization of [Ge9-ER3]3-, [R3E-Ge9-ER3]2-, and [R3E-Ge9-Ge9-ER3]4- (E = Ge, Sn; R = Me, Ph). Angel Ugrinov and Slavi C. Sevov Chem. Eur. J. 2004, 10, 3727-3733 (213 KB)

  • 2003

    • Synthesis and Structure of [K-(12-crown-4)2]2[K-(12-crown-4)]2[Sn9]•4en. Angel Ugrinov and Slavi C. Sevov Appl. Organomet. Chem. 2003, 17, 373-376 (131 KB)

    • [Ge9=Ge9=Ge9=Ge9]8-: A Linear Tetramer of Nine-Atom Germanium Clusters, a Nanorod. Angel Ugrinov and Slavi C. Sevov Inorg. Chem 2003, 42, 5789-5791 (98.3 KB) Highlighted in: Chemical & Engineering News 2003, Sept. 15 Highlighted in: Chemistry & Industry 2003, Oct. 20, p. 28

    • Derivatization of Deltahedral Zintl Ions by Nucleophilic Addition: [Ph-Ge9-SbPh2]2- and [Ph2Sb-Ge9-Ge9-SbPh2]4-. Angel Ugrinov and Slavi C. Sevov J. Am. Chem. Soc. 2003, 125, 14509-14064 (315 KB)

  • 2002

    • [Ge9=Ge9=Ge9]6-: A Linear Trimer of 27 Germanium Atoms. Angel Ugrinov and Slavi C. Sevov J. Am. Chem. Soc. 2002, 124, 10990 (55.1 KB) Highlighted in: Nachrichtenaus der Chemie 2002, p. 1332

    • [Ph2Bi-(Ge9)-BiPh2]2-: A Deltahedral Zintl Ion Functionalized by Exo-Bonded Ligands. Angel Ugrinov and Slavi C. Sevov J. Am. Chem. Soc. 2002, 124, 2442 (36.7 KB) Highlighted in: Chemistry & Industry 2003, Aug. 4, p. 29

  • 2001

    • Stabilization of Ozone-like [Bi3]3- in the Heteroatomic closo-Clusters [Bi3Cr2(CO)6]3- and [Bi3Mo2(CO)6]3-. Xu, L.; Sevov, S.C. J. Am. Chem. Soc. 2001, 123, 4091 (38.4 KB)

  • 2000

    • Heteroatomic Deltahedral Clusters of Main-Group Elements: Synthesis and Structure of the Zintl Ions [In4Bi5]3-, [InBi3]3-, and [GaBi3]3-. Xu, L.; Sevov, S.C. Inorg. Chem. 2000, 39, 5383 (88.9 KB)

    • A Naked Diatomic Molecule of Bismuth, [Bi2]2-, with a short Bi-Bi Bond: Synthesis and Structure. Xu, L.; Sevov, S.C. J. Am. Chem. Soc. 2000, 122, 1838 (39.1 KB) Highlighted in: Nachrichtenaus der Chemie 2000, p. 589

  • 1999

    • Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions. Xu, L; Sevov, S.C. J. Am. Chem. Soc. 1999, 121, 9245 (32 KB) Highlighted in: Chemistry & Industry 1999, Oct. 8, p. 810

• Hybrid Organic-Inorganic Materials
  • 2009

    • Metal-Organic Frameworks with Direct Transition Metal-Sulfonate Interactions and Charge-Assisted Hydrogen Bonds Forbes, T. Z.; Sevov, S.C. Inorg. Chem. 2009, 48, 6873 (476 KB)

  • 2008

    • A Series of Guest-Defined Metal-Complex/Disulfonate Frameworks of Hydrogen-Bonded [Co(en)2(ox)]+ and 2,6-Naphtalenedisulfonate Wang, X-Y; Sevov, S.C. Crystal Growth and Design. 2008, 8, 1265 (2134 KB)

    • Synthesis, Structures, and Magnetic Properties of Metal-Coordination Polymers with Benzenepentacarboxylate Linkers Wang, X-Y; Sevov, S.C. Inorg. Chem. 2008, 47, 1037 (476 KB)

  • 2007

    • Hydrogen-Bonded Host Frameworks of Cationic Metal Complexes and Anionic Disulfonate Linkers: Effects of the Guest Molecules and the Charge of the Metal Complex Wang, X-Y; Sevov, S.C. Chem. Mater. 2007, 19, 4906 (628 KB)

    • Studies of the Mechanism of a Single-Crystal-to-Single-Crystal Reversible Dehydration of a Copper-Carboxylate Framework Wang, X-Y; Scancella, M.; Sevov, S.C. Chem. Mater. 2007, 19, 4506 (532 KB)

    • A Manganese Carboxylate with Geometrically Frustrated Magnetic Layers of Novel Topology Wang, X-Y; Sevov, S.C. Chem. Mater. 2007, 19, 3763 (288 KB)

    • Hydrogen-Bonded Metal-Complex Sulfonate (MCS) Inclusion Compounds: Effect of the Guest Molecule on the Host Framework Wang, X-Y; Justice, R.; Sevov, S.C. Inorg. Chem. 2007, 46, 4626 (328 KB)

  • 2004

    • Reversible Repositioning of Zinc Atoms within Single Crystals of a Zinc Polycarboxylate with an Open-Framework Structure. Hanson, K.; Calin, N.; Bugaris, D.; Scancella, M.; Sevov, S.C. J. Am. Chem. Soc. 2004, 126(34), 10502-10503 (237 KB)

  • 2003

    • VIIIVIV(HPO4)4•enH•H2O: A Mixed-Valence Vanadium Phosphate with an Open Framework. Nathalie Calin, Christian Serre and Slavi C. Sevov J. Mater. Chem. 2003, 13(3), 531-534 (272 KB)

    • [MoV5MoVI7O30(BPO4)2(O3P-Ph)6]5-: A Phenyl-Substituted Molybdenum (V/VI) Boro-Phosphate Polyoxometalate. Capucine Sassoye, Kieran Norton, and Slavi C. Sevov Inorg. Chem. 2003, 42(5), 1652-1655 (152 KB)

    • Novel Mixed-Valence Heteropolyoxometalates: A Molybdenum Diphosphonate Anion [MoV7MoVIO16(O3PPhPO3H)4]3- and its One- and Two-Dimensional Assemblies. Nathalie Calin and Slavi C. Sevov Inorg. Chem. 2003, 42, 7304-7308 (182 KB)

  • 2002

    • Synthesis and Characterization of [Mo7O16(O3PCH2PO3)3]8-: A Mixed-Valent Polyoxomolybdenum Diphosphonate Anion with Octahedrally and Tetrahedrally Coordinated Molybdenum. Eddy Dumas, Capucine Sassoye, Kristin D. Smith, and Slavi C. Sevov Inorg. Chem. 2002, 41, 4029 (116 KB)

    • A Reduced Polyoxomolybdenum Borophosphate Anion Related to the Wells-Dawson Clusters. Dumas, E.; Debiemme-Chouvy, C.; Sevov, S.C. J. Am. Chem. Soc. 2002, 124, 908 (46.2 KB)

    • Synthesis and Characterization of Cs5P[Mo4O14(OH)]2•2H2O: A New Molybdenophosphate Cluster with Face-Sharing MoO6 Octahedra. Dumas, E.; Sevov, S.C. Inorg. Chem. 2002, 41, 144 (72.3 KB)

  • 2001

    • [Co(en)3][B2P3O11(OH)2]: A Novel Borophosphate Templated by a Transition-Metal Complex. Yang, G.-Y.; Sevov, S.C. Inorg. Chem. 2001, 40, 2214 (56.1 KB)

  • 2000

    • Synthesis and Characterization of Four Ethylenediamine-Templated Iron Arsenates. Ekambaram, S.; Sevov, S.C. Inorg. Chem. 2000, 39, 2405 (293 KB)

    • Hydrothermal Synthesis and Characterization of an Ethylenediamine-Templated Mixed-Valence Titanium Phosphate. Ekambaram, S.; Serre, C.; Férey, G.; Sevov, S.C. Chem. Mater. 2000, 12, 444 (166 KB)

  • 1999

    • Hydrothermal Synthesis and Characterization of Two Ammonium-Templated Cobalt Aluminophosphates. Bontchev, R.P; Sevov, S.C. J. Mater. Chem. 1999, 9, 2679 (224 KB)

    • Zinc Phosphate with Gigantic Pores of 24 Tetrahedra. Yang, G.-Y.; Sevov, S.C. J. Am. Chem. Soc. 1999, 121, 8389 (75.3 KB)

    • Chains, Planes, and Tunnels of Metal Diphosphonates: Synthesis, Structure, and Characterization of Na3Co(O3PCH2PO3)(OH), Na3Mg(O3PCH2PO3)F•H2O, Na2Co(O3PCH2PO3)•H2O, NaCo2(O3PCH2CH2CH2PO3)(OH), and Co2(O3PCH2PO3)(H2O). Distler, A.; Lohse, D.L.; Sevov, S.C. J. Chem. Soc. Dalton Trans. 1999, 11, 1805 (799 KB)

    • Organically Templated Mixed-Valent TiIII/TiVI Phosphate with an Octahedral-Tetrahedral Open Framework. Ekambaram, S.; Sevov, S.C. Angew. Chem. Int. Ed. Engl. 1999, 38, 372 (149 KB)

  • 1998

    • Synthesis and Characterization of a New Three-Dimensional Organically Templated Zinc Phosphate, Zn6(PO4)4(HPO4)(H2O)(H3NCH2CH2NH3), with a Chain of Corner-Linked ZnO4 Tetrahedra. Harmon, S.B.; Sevov, S.C. Chem. Mater. 1998, 10, 3020 (147 KB)

    • Synthesis and Characterization of Co3(O2CCH2CH2PO3)2•6H2O, a Metal Carboxylate-Phosphonate with a Framework Structure. Distler, A.; Sevov, S.C. Chem. Commun. 1998, 9, 959 (52.3 KB)

  • 1997

    • Synthesis and Characterization of a New Cobalt Aluminophosphate with an Open-Framework Structure. Bontchev, R.P; Sevov, S.C. Chem. Mater. 1997, 9, 3155 (115 KB)

    • Co2(O3P-CH2-PO3)•H2O: A Novel Microporous Diphosphonate with an Inorganic Framework and Hydrocarbon-Lined Hydrophobic Channels. Lohse, D.L.; Sevov, S.C. Angew. Chem. Int. Ed. Engl. 1997, 36, 1619 Highlighted in: Chemistry & Industry 1997, Nov. 3, p. 876

  • 1996

    • Co5BP3O14: The First Borophosphate with Planar BO3 Groups Connected to PO4 Tetrahedra. Sevov, S.C.; Bontchev, R.P. Inorg. Chem. 1996, 35, 6910 (84.5 KB)

    • Synthesis and Structure of CoB2P3O12(OH)•C2H10N2: The First Metal Borophosphate with an open Framework Structure. Sevov, S.C. Angew. Chem. int. Ed. Engl. 1996, 35, 2630 Highlighted in: Chemistry & Industry 1997, March 3, p. 812

• Intermetallic Compounds
  • 2007

    • In Search of Cyclohexane-like Sn612-: Synthesis of Li2Ln5Sn7 (Ln = Ce, Pr, Sm, Eu) with an Open-Chain Heptane-Like Sn716- Instead Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2007, 46, 4044-4048 (260 KB)

  • 2006

    • Synthesis and Characterization of Na2Ba4Ga2Sb6 and Li13Ba8GaSb12 Iliya Todorov and Slavi C. Sevov Z. Kristallogr. 221 (2006) 521-526 (324 KB)

    • In Search of Benzene-like Sn66-: Synthesis of Na4CaSn6 with Interconnected Cyclohexane-like Sn66-. Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2006, 45, 4478 (202 KB)

  • 2005

    • Heavy-Metal Aromatic and Conjugated Species: Rings, Oligomers, and Chains of Tin in Li9-xEuSn6+x, Li9-xCaSn6+x, Li5Ca7Sn11, Li6Eu5Sn9, LiMgEu2Sn3, and LiMgSr2Sn3. Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2005, 44, 5361 (461 KB)

  • 2004

    • Heavy-Metal Aromatic Rings: Cyclopentadienyl Anion Analogues Sn56- and Pb56- in the Zintl Phases Na8BaPb6, Na8BaSn6, and Na8EuSn6. Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2004, 43, 6490-6494 (89.4 KB)

    • Synthesis, Characterization, and Electronic Structure of Ba5In4Bi5: An Acentric and One-Electron Deficient Phase. Siméon Ponou, Thomas F. Fässler, Gerard Thobías, Enric Canadell, Ara Cho, and Slavi C. Sevov Chem. Eur. J. 2004, 10, 3615-3621 (370 KB)

  • 2003

    • Synthesis and Characterization of the Zintl Pahse Na4Ba3As6 with Isolated As35- Anions. Franck Gascoin and Slavi C. Sevov J. Solid State Chem. 2003, 175, 306 (154 KB)

    • Synthesis and Characterization of Transition-Metal Zintl Phases: Cs24Nb2In12As18 and Cs13Nb2In6As10 with Isolated Complex Anions. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2003, 42, 8567-8571 (79.4 KB)

    • Synthesis and Characterization of Transition-Metal Zintl Phases: K10NbInAs6 and K9Nb2As6. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2003, 42, 904-907 (58.3 KB)

  • 2002

    • Synthesis and Characterization of K38Nb7As24 and Cs9Nb2As6: The First Mixed-Valence Transition Metal Zintl Phases. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 5920 (66 KB) Highlighted in: ChemInform 2003, Jan. 28, 34

    • Niobium-Arsenic Zintl Phases: A6NbAs5 (A = K, Rb, Cs), K6NbTlAs4, and K8NbPbAs5 with Edge-Bridged Niobium-Centered Tetrahedra of Arsenic, [NbAs4M]n- where M = As, Tl, Pb. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 2820-2825 (74.2 KB)

    • KBa2InAs3 with Coexisting Monomers of [In2As7]13- and Their One-Dimensional Polymers. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 2292-2295 (121 KB)

    • Cubane with a Handle: [{In3As4Nb} - As]7- in Cs7NbIn3As5. Franck Gascoin and Slavi C. Sevov Angew. Chem. Int. Ed. 2002, 41, 1232-1234 (99.1 KB)

    • Synthesis, Characterization and Bonding of Ba3Li4Sn8. Bobev, S.; Sevov, S.C. J. Alloys Comp. 2002, 338, 87-92 (399 KB)

    • Naked Clusters of 56 Tin Atoms in the Solid State. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 2002, 124, 3359-3365 (350 KB)

    • Isolated Deltahedral Clusters of Lead in the Solid State: Synthesis and Characterization of Rb4Pb9 and Cs10K6Pb36 with Pb94-, and A3A'Pb4 (A = Cs, Rb, K; A' = Na, Li) with Pb44-. Bobev, S.; Sevov, S.C. Polyhedron 2002, 21, 641-649 (199 KB)

    • Five Ternary Zintl Phases in the Systems Alkali-Metal-Indium-Bismuth. Bobev, S.; Sevov, S.C. J. Solid State Chem. 2002, 163, 436

    • Zintl Phases. Sevov, S.C. in Intermetallic Compounds, Principles and Practice: Progress, Westbrook, J.H.; Freisher, R.L.: Eds.; John Wiley & Sons. Ltd., Chichester, England, 2002, pp. 113-132 (6.10 MB)

  • 2001

    • Synthesis and Characterization of Cs5In3As4 with a Structure of Two Coexisting "Polymorphic" Forms of Different Dimensionality. Gascoin, F.; Sevov, S.C. Inorg. Chem. 2001, 40, 6254 (81.1 KB)

    • Synthesis and Characterization of the Largest Isolated Clusters of Tin, [Sn12]12-, in (AE)Na10Sn12 (AE = Ca or Sr). Bobev, S.; Sevov, S.C. Inorg. Chem. 2001, 40, 5361 (97.4 KB) Highlighted in: Chemistry & Industry 2001, Nov. 19, p. 742

    • Synthesis and Characterization of the "Metallic Salts" A5Pn4 (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn44- and an Extra Delocalized Electron. Gascoin, F.; Sevov, S.C. Inorg. Chem. 2001, 40, 5177 (67.9 KB)

    • Clathrate III of Group 14 Exists After All. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 2001, 123, 3389 (77 KB)

    • Synthesis and Characterization of RbLi7Ge8 with Isolated closo-[Li4Ge12]8- Ions, Lithium-Capped Truncated Tetrahedra of Ge1212-. Bobev, S.; Sevov, S.C. Angew. Chem. Int. Ed. 2001, 40, 1507 (113 KB)

  • 2000

    • Synthesis and Characterization of A3Na10Sn23 (A = Cs, Rb, K) with a New Clathrate-Like Structure and of the Chiral Clathrate Rb5Na3Sn25. Bobev, S.; Sevov, S.C. Inorg. Chem. 2000, 39, 5930 (134 KB) Highlighted in: Chemistry & Industry 2001, Jan. 22, p. 53

    • arachno-[Sn8]6- or closo-[Li2Sn8]4-? Synthesis and Characterization of A4Li2Sn8 (A = Rb, K). Bobev, S.; Sevov, S.C. Angew. Chem. Int. Ed. 2000, 39, 4108 (92.2 KB)

    • Synthesis and Characterization of A3Bi2 (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi2]2-, and an Extra Delocalized Electron. Gascoin, F.; Sevov, S.C. J. Am. Chem. Soc. 2000, 122, 10251 (39.2 KB)

    • Clathrates of Group 14 with Alkali Metals: An Exploration. Bobev, S.; Sevov, S.C. J. Solid State Chem. 2000, 153, 92 (373 KB) Cover Page: J. Solid State Chem. 2000, vol. 153, No. 2

    • Synthesis and Structure of the Alkali-Metal Amalgams A3Hg20 (A = Rb, Cs), K3Hg11, Cs5Hg19, and A7Hg31 (A = K, Rb). Todorov, E.; Sevov, S.C. J. Solid State Chem. 2000, 149, 419 (465 KB)

  • 1999

    • K6Pb8Cd: A Zintl Phase with Oligomers of Pb4 Tetrahedra Interconnected by Cd Atoms. Todorov, E.; Sevov, S.C. Angew. Chem. Int. Ed. 1999, 38, 1775 (111 KB)

    • Cs7In4Bi6: A Zintl Phase Tailored from the PbO-Type Layers of the Parent InBi Compound. Bobev, S.; Sevov, S.C. Inorg. Chem. 1999, 38, 2672 (255 KB)

    • Synthesis and Characterization of Stable Stoichiometric Clathrates of Silicon and Germanium: Cs8Na16Si136 and Cs8Na16Ge136. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 1999, 121, 3795 (36 KB) Highlighted in: Chemistry & Industry 1999, May 17, p. 401

  • 1998

    • Intermetallic Frameworks: Synthesis, Characterization, and Bonding of K0.4Cd2 and Na26Cd141. Todorov, E.; Sevov, S.C. Inorg. Chem. 1998, 37, 6341 (133 KB)

    • Deltahedral Clusters in Neat Solids: Synthesis and Structure of the Zintl Phase Cs4Pb9 with Discrete Pb94- Clusters. Todorov, E.; Sevov, S.C. Inorg. Chem. 1998, 37, 3889 (80.3 KB)

    • Synthesis and Structure of Isolated Silicon Clusters of Nine Atoms. Quéneau, V.; Todorov, E.; Sevov, S.C. J. Am. Chem. Soc. 1998, 120, 3263 (90.3 KB) Highlighted in: C & EN 1998, April 13, p. 40

    • Synthesis and Structure of the Zintl-Phase K4Pb9 Containing Isolated Pb94- Clusters of Two Different Geometries. Quéneau, V.; Sevov, S.C. Inorg. Chem. 1998, 37, 1358 (98.9 KB)

  • 1997

    • Synthesis, Characterization, and Bonding of Heteroatomic Clusters: Na13Cd20E7 (E = Pb, Sn), a Further Example of a Structure Containing Empty Icosahedra without an Element of Group 13. Todorov, E.; Sevov, S.C. Inorg. Chem. 1997, 36, 4298 (136 KB) Highlighted in: Chemistry & Industry 1997, Oct. 20, p. 83

    • Ge94-: A Deltahedral Zintl Ion Made in the Solid State. Quéneau, V.; Sevov, S.C. Angew. Chem. Int. Ed. Engl. 1997, 36, 1754

    • Cs6Ge8Zn: A Zintl Phase with Isolated Heteroatomic Clusters of Ge8Zn. Quéneau, V.; Sevov, S.C. J. Am. Chem. Soc. 1997, 119, 8109 (143 KB)

    • Synthesis, Characterization, Electronic Structure, and Bonding of Heteroatomic Deltahedral Clusters: Na49Cd58.5Sn37.5, A Network Structure Containing The First Empty Icosahedron without a Group 13 Element and the Largest closo-Deltahedron. Todorov, E.; Sevov, S.C. J. Am. Chem. Soc. 1997, 119, 2869 (185 KB)

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Intermetallic Compounds | Metal Clusters in Solution | Hybrid Organic-Inorganic Materials